Abstract
Background: Sulfur-containing compounds are widespread among natural products and bioactive substances, and also useful ligands in asymmetric catalysis.
Objectives: In this context, different methods for the preparation of oxazolidine- and oxazoline-2-thiones and their more recent applications are reviewed.
Conclusions: In this survey, novel rearrangements and new reactions have also been summarized since 2007 until 2016.
Keywords: Oxazolidine-2-thiones, oxazoline-2-thiones, chiral auxiliary, applications, asymmetric synthesis, diastereoselectivity.
Current Organic Synthesis
Title:Oxazolidine- and Oxazoline-2-thiones: An Update
Volume: 14 Issue: 8
Author(s): Estibaliz Sansinenea*, Aurelio Ortiz, Patrick Rollin and Sandrina Silva*
Affiliation:
- Facultad de Ciencias Quimicas de la Benemerita Universidad Autonoma de Puebla, Puebla Pue., 72570,Mexico
- Department of Chemistry, Federal University of Sao Carlos, Sao Paulo 13565-905,Brazil
Keywords: Oxazolidine-2-thiones, oxazoline-2-thiones, chiral auxiliary, applications, asymmetric synthesis, diastereoselectivity.
Abstract: Background: Sulfur-containing compounds are widespread among natural products and bioactive substances, and also useful ligands in asymmetric catalysis.
Objectives: In this context, different methods for the preparation of oxazolidine- and oxazoline-2-thiones and their more recent applications are reviewed.
Conclusions: In this survey, novel rearrangements and new reactions have also been summarized since 2007 until 2016.
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Cite this article as:
Sansinenea Estibaliz *, Ortiz Aurelio , Rollin Patrick and Silva Sandrina *, Oxazolidine- and Oxazoline-2-thiones: An Update, Current Organic Synthesis 2017; 14 (8) . https://dx.doi.org/10.2174/1570179414666170503165413
DOI https://dx.doi.org/10.2174/1570179414666170503165413 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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