Abstract
Most organic lithium compounds exist as aggregates. Many lithium compounds also form mixed aggregates with other lithium compounds, which have structures and properties that are different from either of the parent lithium compounds. Mixed aggregate formation can alter the product distribution and rate of reactions involving lithium dialkylamides.
Keywords: organolithium, lithium amide, lithium enolate, mixed aggregates
Mini-Reviews in Organic Chemistry
Title: Mixed Aggregates of Organolithium Compounds
Volume: 1 Issue: 2
Author(s): Lawrence M. Pratt
Affiliation:
Keywords: organolithium, lithium amide, lithium enolate, mixed aggregates
Abstract: Most organic lithium compounds exist as aggregates. Many lithium compounds also form mixed aggregates with other lithium compounds, which have structures and properties that are different from either of the parent lithium compounds. Mixed aggregate formation can alter the product distribution and rate of reactions involving lithium dialkylamides.
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Cite this article as:
Pratt M. Lawrence, Mixed Aggregates of Organolithium Compounds, Mini-Reviews in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570193043488863
DOI https://dx.doi.org/10.2174/1570193043488863 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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